| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 | 25권 1호, p.611 |
| 발표분야 | 열역학(Thermodynamics) |
| 제목 | Encapsulation of Methacrolein and Gaseous Guests in Clathrate Hydrates and Their Spectroscopic Investigations |
| 초록 | Here, new structure II (sII) clathrate hydrates with methacrolein in the presence of gaseous guest (CH4, N2, O2 or CO2) were characterized. The crystal structure and guest distributions of binary (methacrolein + gaseous guests) clathrate hydrates were identified through spectroscopic tools. The crystal structure of binary (methacrolein + gaseous guests) clathrate hydrates was identified as cubic Fd3m structure through powder X-ray diffraction patterns. We revealed that the inclusion of methacrolein and gaseous guests including CH4, N2, O2 or CO2 could be monitored in the large and the small cages of sII hydrates through Raman spectroscopy. The conformation of methacrolein in the large cages of sII hydrates was also analyzed via Raman spectroscopy, revealing s-trans conformer of methacrolein in the large cages of sII hydrates. We also checked the thermodynamic stability of binary (methacrolein + gaseous guest) clathrate hydrates. KEYWORDS clathrate hydrate, methacrolein, guest, spectroscopic investigation |
| 저자 | 차민준1, 박기훈1, 윤여범2, 안윤호3 |
| 소속 | 1강원대, 2현대중공업, 3KAIST |
| 키워드 | 열역학; 상평형 |
| 원문파일 | 초록 보기 |
