화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 봄 (04/22 ~ 04/24, 제주 ICC)
권호 21권 1호, p.480
발표분야 에너지
제목 Ultrathin sandwich-like MoS2@N-doped carbon nanosheets for the anode of lithium ion battery
초록 We report a simple and scalable process to synthesize the core–shell nanostructure of MoS2@N-doped carbon nanosheets (MoS2@C), in which polydopamine is coated on the MoS2 surface and then carbonized. Transmission electron microscopy and Raman spectroscopy reveals that the as-synthesized MoS2@C possesses a nanoscopic and ultrathin layer of MoS2 sheets with a thin and conformal coating of carbon layers (∼3 nm). The MoS2@C demonstrates a superior electrochemical performances as an anode material for lithium ion batteries compared to exfoliated MoS2 and bulk MoS2 samples. This unique core–shell structure is capable of excellent delivery Li+ ion in charging–discharging process: a specific capacity as high as 1239 mA h g−1, a high rate of charging-discharging capability even at a high current rate of 10 A g−1 while retaining 597 mA h g−1, and a good cycle stability over 200 cycles at a high current rate of 2 A g−1.
저자 정재민1, 박견주1, 석승환1, 최봉길2, 김도현1
소속 1한국과학기술원, 2강원대
키워드 Molybdenum disulfide; N-doped carbon; 2-D Nanosheet; Lithium ion battery
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