| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis of pH-sensitive block copolymer : Poly(ethylene oxide)-b-poly(sulfadimethoxinyl methacrylamide) |
| 초록 |
Chain-end functionalized polymers have received a great deal of attention in the polymer chemistry field. Among them, ω-halogenated polymer can be used for the synthesis of reversible addition fragmentation transfer (RAFT) agent. We have synthesized PEO-based RAFT agent through “living” poly(ethylene oxide) via anionic polymerization and its chain-end functionalization. The polymeric alkoxide was terminated with 2-bromopropionyl bromide leading to the generation of ω-brominated PEO. The ω-brominated polymer can be converted to the RAFT agent through the reaction with potassium ethyl xanthogenate. A methacrylate type of sulfadimethoxine monomer was synthesized by the reaction of methacryloyl chloride with sulfadimethoxine in water/acetone (1 : 1). The PEO-based RAFT agent was used to polymerize the sulfonamide monomer using AIBN in DMF. The resulting block copolymer showed the pH-sensitive property. In this presentation, we will report the preliminary results. |
| 저자 |
김성우, 시디크아부바카, 이유라, 김현준, 박현종, 이재열, 강호정, 김정안
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| 소속 |
경희대 |
| 키워드 |
ω-halogenated polymer; RAFT agent; pH-sensitive block copolymer
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| E-Mail |
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