화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 기능성 고분자
제목 Synthesis of solvent-free urethane-acrylate IPN type adhesives with soft and rigid dual polymer networks
초록 Currently, there are increasing interests in eco-friendly adhesives such as zero VOCs and solvent-free adhesives in various industries. Among them, solvent-free adhesives of a single composition using acrylate monomers suffered from many difficulties. In this study, solvent-free urethane-acrylate IPNs adhesives with unique structure in which urethane polymer networks with soft properties and acrylate polymer networks with hard properties was entangled were studied. First, PPG-based urethane prepolymers were polymerized using acrylate monomers as the solvent, and final solvent-free urethane-acrylate IPNs adhesives were prepared by photo-polymerizing the acrylate monomer. Polymerizations of urethane and acrylate polymer were confirmed by 1H-NMR and FT-IR methods, and the properties of OH-terminated urethane prepolymers were confirmed using GPC, viscometer and potentiometer. Through the possibilities of application in real life as paint binders and adhesives were confirmed.
저자 이동엽1, Henok Getachew Girma2, 김예진1, 류가연1, 공호열1, 황도훈1, 임보규2
소속 1한국화학(연), 2부산대
키워드 Polyurethane; Polyol; IPNs; Binders
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