학회 |
한국고분자학회 |
학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
권호 |
46권 2호 |
발표분야 |
기능성 고분자 |
제목 |
Synthesis of solvent-free urethane-acrylate IPN type adhesives with soft and rigid dual polymer networks |
초록 |
Currently, there are increasing interests in eco-friendly adhesives such as zero VOCs and solvent-free adhesives in various industries. Among them, solvent-free adhesives of a single composition using acrylate monomers suffered from many difficulties. In this study, solvent-free urethane-acrylate IPNs adhesives with unique structure in which urethane polymer networks with soft properties and acrylate polymer networks with hard properties was entangled were studied. First, PPG-based urethane prepolymers were polymerized using acrylate monomers as the solvent, and final solvent-free urethane-acrylate IPNs adhesives were prepared by photo-polymerizing the acrylate monomer. Polymerizations of urethane and acrylate polymer were confirmed by 1H-NMR and FT-IR methods, and the properties of OH-terminated urethane prepolymers were confirmed using GPC, viscometer and potentiometer. Through the possibilities of application in real life as paint binders and adhesives were confirmed. |
저자 |
이동엽1, Henok Getachew Girma2, 김예진1, 류가연1, 공호열1, 황도훈1, 임보규2
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소속 |
1한국화학(연), 2부산대 |
키워드 |
Polyurethane; Polyol; IPNs; Binders
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E-Mail |
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