화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자합성
제목 Synthesis of n-octadecane/ Polyurea core-shell nanoparticles via Miniemulsion Interfacial Polycondensation reaction
초록 N-octadecane/polyurea (PCM/PU) core-shell nanoparticles were successfully synthesized via interfacial polymerization process. Among the amount of poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) was used to maintain the colloidal stability and used to control of shell thickness of PCM/PU core-shell nanoparticles. In the manufacturing process of the core / shell nanoparticle existing, we have to adjust the thickness of the shell by the adjustment ratio of monomer and core material. However, in our process, the thickness of the shell, which is polymerized at the interface, depending on the content of PSSMA that change is the difference from the previous step. Synthesis mechanism of PCM/PU core-shell nanoparticle confirmed DSC(Differential Scanning Calorimeter), TGA(Thermal gravity analysis), SEM(Scanning Electron Microscopy), by TEM(Transmission Electron Microscopy) analysis
저자 국준원1, 정인우2, 고원건1, 김중현1
소속 1연세대, 2경북대
키워드 octadecane; polyurea; PSSMA; shell thickness
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