| 학회 |
한국화학공학회 |
| 학술대회 |
2021년 봄 (04/21 ~ 04/23, 부산 BEXCO) |
| 권호 |
27권 1호, p.576 |
| 발표분야 |
에너지 환경 |
| 제목 |
Incorporation of the Ni@C core-shell nanoparticles to the solar to hydrogen generation system based on CIGS sub-module |
| 초록 |
Continuous hydrogen generation from electrocatalytic water splitting, where energy is supplied from the photovoltaic cell is a promising technology for uninterrupted fuel production and storage. However, the development and optimization of economically feasible bifunctional electrocatalyst and solar cells remain challenging. In this work, we develop cheap Ni@C core@shell nanoparticles using an electrical explosion of wires method and apply it as a bifunctional catalyst for the overall water-splitting reaction. The thickness of the carbon shell can be controlled via experimental parameters. Depending on the thickness, carbon shell can effectively protect the metallic core from oxidation, while providing a porous structure supplying high surface area, which in turn enhances catalytic activity. Furthermore, we manufactured CIGS cells and constructed a suitable CIGS sub-module to construct a solar to hydrogen generation system. Combining CIGS sub-module and Ni@C-based electrolyzer we achieved overall solar to the hydrogen conversion efficiency of 8.14%, with 13.1% efficiency of sub-module at the operating point. |
| 저자 |
Ngo Quang Tung1, Oleksii Omelianovych1, Nguyen Ngoc Anh1, Nguyen Van Toan1, Trinh Van Huy1, 이경과2, Liudmila Larina1, 이규복1, 최호석1
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| 소속 |
1충남대, 2한국원자력(연) |
| 키워드 |
에너지 |
| E-Mail |
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| 원문파일 |
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