화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 고분자합성
제목 Single-walled carbon nanotube dispersion in various polar solvents using quaternized poly((furfurylmethacrylate)-co-(2-(dimethylamino)ethylmethacrylate)) p(FMA-co-QDMAEMA) as polymeric dispersant
초록 We synthesized polymeric dispersant, poly((furfuryl methacrylate)-co-(2-(dimethylamino)ethyl methacrylate)) (p(FMA-co-DMAEMA)) and quaternized p(FMA-co-DMAEMA) (p(FMA-co-QDMAEMA) to disperse single-walled carbon nanotubes (SWCNTs) from bundled state to individual. p(FMA-co-DMAEMA) could disperse SWCNTs in only THF, In order to utilize in many fields, we dispersed SWCNT in various polar solvents, such as ethylene glycol, methanol, water and dimethylformamide using p(FMA-co-QDMAEMA) as polymeric dispersant. The chemical structures of the synthesized and modified polymeric dispersants were confirmed using 1H NMR and molecular weight by GPC. The dispersion quality of SWCNTs by p(FMA-co-QDMAEMA) was estimated using a particle stability analyzer, UV-vis-NIR spectroscopy, transmission electron microscopy, and atomic force microscopy. The diameters and degree of defects of dispersed SWCNTs were estimated using Raman spectroscopy.
저자 이영실1, 한종훈2, Aruna Kumar Mohanty3, 이태헌3, 백현종3, 박재현3
소속 1금오공과대, 2전남대, 3부산대
키워드 CNT dispersion; Polymeric dispersant; Quaternization
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