| 초록 |
Diverse high ring strain energy (RSE) groups embedded active plasticizers (APs) are synthesized since cyclic alkyl groups are expected to be a potential energetic candidate as well as lower impact sensitivity than conventional energetic groups such as nitro, nitrite and nitrate. To solve the migration and exudation of conventional energetic plasticizers, a highly reliable and practical reaction, Huisgen 1,3-dipolar cycloaddition, was employed as a coupling protocol to achieve the chemical connection with polymeric matrix. These APs are succesfully applied into azido prepolymer-based polyurethane (PU) binder systems by improving processibility, forming well-dispersed mophology, being manipulable pot life, achieving perfect integrity with polymer matrix, maintaining thermal stability and mechanical properties of pristine binder as elastomer. |
