| 학회 |
한국고분자학회 |
| 학술대회 |
2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
47권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
A retro Diels-Alder Reaction Triggered Self-assembly |
| 초록 |
Despite many studies have been conducted on their chemical application, Diels-Alder (DA) and retro Diels-Alder (rDA) reactions have been vastly unexplored in promoting self-assembly process. Herein we suggest the first example of a rDA reaction-triggered self-assembly method. Removal of the steric bulkiness due to the bridged bicyclic DA adduct by the rDA reaction yields two building blocks that spontaneously self-assembled to form a supramolecular polymer. By employing photopolymerizable diacetylene as building blocks, we demonstrated the efficiency of the rDA-based self-assembly strategy. The entire process of rDA reaction and photopolymerization was confirmed by NMR and Raman spectroscopy. Generation of reactive functional groups (maleimide/furan) that can be used for further modification of the supramolecular polymer is an additional advantage of the rDA-based approach. These functional groups were used to fabricate stimulus-responsive selective and tunable colorimetric sensors. |
| 저자 |
박재영, 허정무, 김종만
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| 소속 |
한양대 |
| 키워드 |
retro Diels-Alder; Triggered self-assembly; Diacetylene; Colorimetric sensor
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| E-Mail |
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