화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 기능성 고분자
제목 Decoding Liquid Crystal Oligomer Phase Transitions: Towards Molecularly-Engineered Shape Shifting Materials
초록 This work details an integrated investigation of liquid crystal (LC) oligomers that combines experiments and molecular dynamics simulations for obtaining a detailed understanding of the molecular structure of LC oligomers and the mechanism underlying their phase transition temperatures. The results showed that increasing the length of the extender decreases Tni for LC oligomers and amplifies the decrease of Tni in LC oligomers when the spacer length is short. We infer that the combination of spacer and extender changes the shape anisotropy of LC oligomers, changing packing behavior of constituent mesogens, thus affecting their ability to transition from the isotropic to the nematic phase.
저자 궈위엔항, 안석균, 이지은
소속 부산대
키워드 Liquid Crystal Elastomer; shape changing materials
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