| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
The Study on Polymer Electrolyte Membrane Characteristics of Polyacrylate Bearing Phosphonic Acid Group |
| 초록 |
A novel series of phosphonated polymers which had phosphonic acid groups via flexible pendant side chains (PAEPA, PABPA, and PAHPA) was synthesized by the radical polymerization of AEPN, ABPN and AHPN, respectively, followed by hydrolysis with trimethylsilyl bromide.. Among the three polymers, the cross-linked poly[6-(acryloyloxy)hexylphosphonic acid] (PAHPA) membrane prepared by the recombination of polymer radicals with benzoyl peroxide as a radical initiator showed excellent proton conductivity comparable to that of the Nafion 117 membrane in the range of 30–80% relative humidity (RH) at 80 C, regardless of the significantly low water uptake behavior. Furthermore, well-defined phase separation between the hydrophobic and hydrophilic domains was clearly observed by scanning transmission electron microscopy (STEM) and synchrotron X-ray scattering measurements. |
| 저자 |
김창섭1, 이문호1, 노예철2, 정정운2, 권원상2, 안병철2, 김영용1, 김종현2, 위동우1, Tomoya Higashihara3, Namiko Fukuzaki3, Youko Tamuraand3, Kazuhiro Nakabayashi3, Satoshi Nakazawa3, Shigeaki Murata4, Mitsuru Ueda4
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| 소속 |
1포항공대 첨단재료과학부, 2포항공대 화학과, 3Tokyo Institute of Technology, 4Japan Science and Technology Agency (JST) |
| 키워드 |
fuel cell; phosphonated polymer; flexible pendant; Polymer Electrolyte Membrane
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| E-Mail |
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