화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 고분자구조 및 물성
제목 Improved Plasmonic Properties of Highly Conductive Polymers Confined in Nanopores
초록 Conductive polymer such as poly(3,4-ethylenedioxythiophene:sulfate) (PEDOT:Sulf) can provide high electrical conductivity and metallic behavior. Due to its metal-like behavior, PEDOT:Sulf nanodisks can function as plasmonic metasurface only with organic materials and act tunable by redox reactions. However, it is still necessary to improve the plasmonic properties by increasing the electrical conductivity in the way as chain alignment and low defects. Here, we propose high density array of PEDOT:Sulf nanopillars based on anodized aluminum oxide (AAO) template for enhanced electrical conductivity and plasmonic properties. PEDOT:Sulf nanopillars have improved electrical conductivity by effectively aligning chains in nanopore, which improves the plasmonic properties of PEDOT:Sulf. Also, we expect to show complex and anisotropic permittivity by chain alignment along vertical direction, it can be applied to hyperbolic metamaterials.
저자 김상훈, 김진곤
소속 포항공과대
키워드 anodized aluminum oxide (AAO); conductive polymer; confinement effect; plasmonic metamaterials
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