화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 기능성 고분자
제목 Synthesis and Properties of Imine Group Containing Reactive Mesogens with Negative Wavelength Dispersion Birefringence
초록 In this study, the H-shape reactive mesogen molecular structure including the C=N bond was designed so that the birefringence increases as the wavelength increases. The molecular structure used in the direction perpendicular to the long axis was synthesized by introducing a photocrosslinkable functional group. For the molecular structure of the long axis, imine bonds were synthesized through a Schiff base using various kinds of diamines including aromatic compounds. The molecular structure of the H-shape containing the imine bond was confirmed by NMR, UV-Vis, DSC, and FAB-MS. When H-shape reactive mesogen compound containing an imine bond was mixed with a positive dispersed host liquid crystal, negative dispersion properties were observed.
저자 김자원1, 고원건2, 가재원2
소속 1한국화학(연), 2연세대
키워드 anti reflection film; retardation film; negative dispersion liquid crystal
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