| 학회 | 한국화학공학회 |
| 학술대회 | 2018년 봄 (04/25 ~ 04/27, 창원컨벤션센터) |
| 권호 | 24권 1호, p.548 |
| 발표분야 | 에너지 환경 |
| 제목 | MFI-type zeolite coated ceramic tubular membrane developed for generation of two electron mediators concurrently |
| 초록 | The robustness and high volumetric conversion performance of tubular electrochemical reactor was disclosed to generate a single mediator. The present work explains two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated ceramic membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally. Key words: Zeolite tubular membrane, tubular electrochemical cell, two mediator generation, paired electrolysis |
| 저자 | 문일식, A.G. Ramu, G. Muthuraman |
| 소속 | 순천대 |
| 키워드 | 에너지 환경 |
| 원문파일 | 초록 보기 |
