| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 | 25권 1호, p.556 |
| 발표분야 | 에너지 환경(Energy and Environment) |
| 제목 | Metal ion mediator crossover elimination by MFI-type zeolite coated ceramic tubular membrane for effective generation of two electron mediators |
| 초록 | Elimination of metal ion crossover via membrane is a big challenging part in many field. The present work attempt to eliminate two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- crossover by a tubular MFI-type zeolite coated ceramic membrane in a divided electrochemical cell. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved by paired electrolysis and confirmed by ORP change. No metal ion crossover via MFI-zeolite coated cerami membrane confirmed by UV-visible spectral analysis. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. The pH change could be the reason for no migration of Co(II) or [Ni(II)(CN)4]2-. Key words: MFI-zeolite tubular membrane, tubular electrochemical cell, two mediator generation, no-crossover |
| 저자 | 이보열, G. Muthuraman, A.G. Ramu, 문일식 |
| 소속 | 순천대 |
| 키워드 | 에너지 환경 |
| 원문파일 | 초록 보기 |
