화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_환경·에너지
제목 Study of one side coated MFI-zeolite on a ceramic tube in concurrent generation of two electron mediator
초록 Effective ion cross over prevention through a membrane is a hot topic. Here in, effect of one side MFI-zeolite coated ceramic tube in generation of two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- and its crossover was analyzed. Through the one side coated MFI-type zeolite tubular membrane, electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved by paired electrolysis and confirmed by ORP change. No metal ion crossover via one side coated MFI-zeolite ceramic membrane was confirmed by UV-visible spectral analysis. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the one side coated MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement.
저자 이보열, G. MUTHURAMAN, A.G.Ramu, 문일식
소속 순천대
키워드 MFI-zeolite tubular membrane; tubular electrochemical cell; two mediator generation; no-crossover
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