화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 Programmable Soft Materials and Their Applications
제목 Shape Memory Vitrimers for Extrusion-Based 4D Printings with Reprocessable, Recyclable and Weldable Properties
초록 Vitrimers are attracting attention because of their cross-linked polymer architecture with reprocessability and recyclability based on an associative covalent adaptable network (CAN). Here, the vitrimers are prepared and the properties are tuned to make these materials extrudable/printable. The prepared vitrimers are utilized as a functional “ink” for extrusion-based 4D printing (Fused Deposition Modeling (FDM) or Fused Filament Fabrication (FFF)). The rheological properties of the vitrimers are adjusted by changing the chemical formulation and network architecture tailoring. Using the intrinsic cross-linked networks of the vitrimers, shape memory performance is demonstrated and used in 4D printing applications. A bond exchange reaction leads to the topological rearrangement of vitrimers, thus allowing them to be reprocessed, reshaped, recycled, and reprinted.
저자 박성민, 김동균, 김용석
소속 한국화학(연)
키워드 Shape Memory Polymers; Vitrimers; 4D Printings
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