| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_고분자 |
| 제목 |
Development of cross-linked membranes via thiol-ene click reaction using thiol-terminated sulfonated poly(arylene ether sulfone) for proton exchange membrane |
| 초록 |
Thiol-terminated sulfonated poly(arylene ether sulfone) (SH-SPAES) are synthesized to fabricate end-group cross-linked structure proton exchange membrane. Acrylo-polyhedral oligomeric silsesquioxane (A-POSS) is used as a multifunctional cross-linker via thiol-ene click reaction. SH-SPAES is prepared by stepwise reactions between phenoxide-terminated SPAES and end capping reagents such as decafluorobiphenyl and thiobisbenzenethiol. The cross-linked membranes exhibit improved physicochemical properties compared with linear SPAES having degree of sulfonation for 70 mol%. Under 90 oC, 100%RH condition, the power density values at 0.5 V of MEAs for C-SPAES-10 and -20 are 1.22 and 1.09 A cm-2, respectively. |
| 저자 |
조경화, 김기현, 김정환, 한주성, 이현희, 김혜진, 이종찬
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| 소속 |
서울대 |
| 키워드 |
Thiol-ene click reaction; sulfonated poly(arylene ether sulfone); cross-linking; proton exchange membrane
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| E-Mail |
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