| 학회 |
한국공업화학회 |
| 학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
26권 1호 |
| 발표분야 |
포스터-환경·에너지 |
| 제목 |
Low temperature PET glycolysis |
| 초록 |
In this presentation, we will discuss a new catalytic method to depolymerize post-consumer PET into bis(2-hydroxyethyl) terephthalate(BHET). Addition of a green co-solvent to the glycolysis system facilitated catalytic conversion of PET into BHET at 153℃, which temperature is much lower than that of conventional glycolysis(>197℃). Several inexpensive metal salts or organic guanidine bases were used as effective catalysts for the low-temperature glycolysis. Under the optimal reaction conditions, PET completely decomposed within 2 h and the final yield of BHET was more than 86% at 153℃. Based on the most probable reaction steps, a kinetic model mechanistically describing the overall reaction behavior was developed. |
| 저자 |
Le Thi Hong Ngan1, 조예림1, 조정모1, 박상태2, 김재경2, 이종용2
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| 소속 |
1한국화학(연), 2리뉴시스템 |
| 키워드 |
PET glycolysis; chemical recycling; green co-solvent; kinetic model; intermolecular interaction
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| E-Mail |
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