| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
콜로이드계면화학_포스터 |
| 제목 |
Heterogeneous Rubpy Molecular Catalyst for CO2 Reduction Promoted by Surface Plasmon Resonance of Gold Nanoparticles |
| 초록 |
This work introduces a CO2 reduction catalysis using a ruthenium bipyridine molecular catalyst assembled on the surface of TiO2 junctioned with a gold nanostructure. The ligand carrying phosphonate groups make the molecular catalyst successfully immobilized on highly oxophilic TiO2 surface. Light irradiation (＞ 400 nm) promotes hot electron generation from gold nanoparticles by surface plasmon resonance, and molecular catalyst receives the electrons to reduce CO2 into formic acid in aqueous electrolyte. Moreover, the advantage of the use of a molecular catalyst is a high selectivity (＞90 % selectivity) toward a desired product. The results represent our photochemical CO2 reduction method is a sustainable and environment-friendly strategy to use solar energy in producing useful resources. This work was supported by the Korea CCS R&D Center (KCRC) grant funded by the Korea government (Ministry of Science, ICT & Future Planning) (NRF-2014M1A8A1049303). |
| 저자 |
전휘석, 남윤성
|
| 소속 |
한국과학기술원 (KAIST) 신소재공학과 |
| 키워드 |
carbon dioxide; molecular catalyst; titania; surface plasmon resonance; formic acid
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| E-Mail |
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