| 학회 |
한국고분자학회 |
| 학술대회 |
2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
47권 1호 |
| 발표분야 |
콜로이드 및 분자조립 부문위원회 |
| 제목 |
Frank-Kasper mesoatomic crystals from apex-dependent dendron assembly |
| 초록 |
We design and present a strategy to create Frank-Kasper (FK) phases from simple second-generation (G2) dendrons possessing different apex functionalities (Xs) that modulate core interactions among the apex groups. The dendrons of G2-X were synthesized by a convergent method and post-functionalized at terminal X to have CONH2, CH2OH, and CH2NH2 which are in decreasing order of core interactions (or H-bonding). With a versatile modular platform of G2-X, we seek to answer a question about how enthalpic and entropic contributions affect dendron assemblies. In-situ small-angle X-ray scattering (SAXS) and FT-IR spectroscopy are measured to trace temperature-dependent assembly phases with respect to the core interactions. |
| 저자 |
전태석1, 박현준1, 장우동1, Byeongdu Lee2, 류두열3
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| 소속 |
1연세대, 2Argonne National Laboratory, 3US |
| 키워드 |
dendrons; assemblies; Frank-Kasper; sphere-packing
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| E-Mail |
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