| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Sustainable Polythionoesters via Ring-Opening Polymerization of Thionolactones Using Heterogeneous Catalysts |
| 초록 |
The utilization of sustainable polymers aims to address the environmental challenges that are inherently associated with traditional petroleum-based polymers by using sustainable and renewable feedstocks. Thionolactones synthesized from lactones by S/O substitution attracted attention owing to the crosslinking nature and subsequent biodegradability and metal recovery application. Here we have synthesized thionolactones and utilized them for the ring-opening polymerization (ROP) and subsequent investigation of its kinetics. Anhydrous ethylene glycol is used to initiate the ROP of thionolactones in the presence of a heterogenous catalyst. Monomers and polymers were characterized using proton nuclear magnetic resonance spectroscopy, Fourier-transform infrared spectroscopy, and gel permeation chromatography. The kinetic studies indicate that the reaction rate is first-order with respect to the concentration of monomer and initiator. |
| 저자 |
RIMESH AUGUSTINE1, 김일2, 박진2
|
| 소속 |
1Pusan National Univ., 2부산대 |
| 키워드 |
thionoesters; ring-opening polymerization; biodegradable polymers; sustainable monomers.
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| E-Mail |
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