화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 우수논문(구두)_박사과정
제목 Visualization of Reaction Kinetics of Low Temperature Thiol-Epoxy Cross-Linking Reaction by Using pH Responsive Epoxy Resin
초록 The reaction kinetics of model thiol-epoxy polymer networks (TEPNs) was visualized by tracking pH variation occurred during cross-linking reaction. Color transition of TEPNs was monitored in real-time and the result was correlated with other characterization techniques such as Fourier transform infrared (FT-IR) spectroscopy, isothermal differential scanning calorimetry (DSC), and oscillational rheology measurements. Influence of glass transition temperature (Tg) on reaction kinetics of TEPNs during the low temperature cross-linking reaction was investigated by employing various TEPNs having different functionality of cross-linkers.
저자 이태희1, 김진철2, 박영일2, 백충기1, 노승만2
소속 1울산과학기술원, 2한국화학(연)
키워드 thiol-click chemistry; thiol-epoxy curing; visualization of cross-linking reaction; pH responsive
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