| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Mesoscale Lattices Assembled from Charge-Tunable Block Copolymer Micelles |
| 초록 |
Recent studies revealed that block copolymer (BCP) microdomains are capable of being organized into unusual symmetries such as Frank-Casper phases. These unique structures result from a compromise between domain geometry and space-filling constraint; in other words, the deformability of soft matter. Our mesoscale micellar lattices co-assembled from the blends of oppositely charged BCPs demonstrate the nature of deformable soft materials in a distinctive way. The micellar structures and interactions of BCPs in selective solvents can be finely tuned by controlling the charge density such that the micelles further assemble into pseudo-crystalline arrays. The micellar lattices show unconventional packing symmetry and strikingly clean facet formation compared with hard-sphere counterparts reported so far. It is believed that such deviation in the micellar lattices arises from the soft nature of BCPs which can be readily deformed upon swelling. |
| 저자 |
차국헌1, 최수형2, 최제원1, 김세영1
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| 소속 |
1서울대, 2홍익대 |
| 키워드 |
Block Copolymers; Micelles; Lattices
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| E-Mail |
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