화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 분자전자 부문위원회 II
제목 Temperature dependence between light-induced electron spin resonance spin density and photocurrent in perovskite solar cell
초록 Photo-induced charges accumulated at the interface between perovskite layer and hole transport layer can be detected by light–induced electron-spin-resonance (LESR) spin density in a perovskite solar cell (PSC). The LESR spectra, which show thermal dependence, were diminished as temperature decreased from room temperature to 170 K in a PSC and disappeared below ~170K. At the same time, the photocurrent was decreased only ~25% between room temperature and 170K. According to the variation of LESR spin density and photo current at the different temperature, we concluded that decreased transient or steady photocurrent at the low temperatures mainly attributed to the delocalized holes trapped at the interface between perovskite and HTL.
저자 이승주1, 남계춘2, 전남중1
소속 1한국화학(연), 2전남대
키워드 Perovskite; Photoconductivity; solar cells; phase transitions; Electron paramagnetic resonance spectroscopy
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