화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-콜로이드·계면화학
제목 Synthesis of Associative Silica Nanoplatelets with Controllable Wettability Using Hexagonal Structured Polypeptide Templates
초록 Colloidal particleswith 2-dimensional geometry exhibit high adhesion energy at the interface sothat there have been tries to synthesize new types of particles with a tailoredplatelet structure. Herein, we introduce an approach to synthesize associative silicananoplateltes (ASNPs) with controllable wettability. For this, we synthesizedsilica nanoplatelets (SiNPs) by silicification on hexagonal platelet-structuredpolypeptide templates via a condensation reaction. A suitable surfacewettability of the SiNPs was achieved by the combined grafting of3-aminopropyltriethoxysilane (APTES) and hexyltrimethoxysilane (HTMS) throughsilane coupling reactions. Taking advantage of high adhesion energy coming fromthe platelet-geomerty of SiNPs, we could easily obtain stable O/W and W/O typePickering emulsions. These results highlighted that the SiNPs developed in thisstudy could have great potential for applications to complex multiphasic fluidsystems.
저자 김하정, 성민철, 김진웅
소속 성균관대
키워드 silica nanoplatelets; templated silicification; Pickering emulsion
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