학회 |
한국고분자학회 |
학술대회 |
2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO)) |
권호 |
45권 1호 |
발표분야 |
고분자구조 및 물성 |
제목 |
A Highly Self-Healable Heterocyclic Elastomer Based on Isosorbide Oligomer With Excellent Surface Hardness |
초록 |
A new heterocyclic elastomer based on isosorbide oligomer (HEIO) is synthesized and its self-healing and mechanical properties are studied. To prepare HEIO, an isosorbide oligomer with hydroxyl groups at both ends is synthesized and reacted with acrylate-based polyol (aPo) and crosslinker with multiple isocyanate groups (Xlinker). To compare the self-healing and mechanical properties, aPo is reacted with Xlinker to prepare conventional elastomer (CE) and isosorbide and aPo are reacted with Xlinker to generate heterocyclic elastomer with randomly distributed isosorbide moiety (HEI). Interestingly, HEIO exhibits outstanding self-healing efficiency compared to CE without isosorbide moiety. In addition, HEIO shows more enhanced surface hardness than CE or HEI. These results demonstrate that the conventional elastomer can achieve both excellent self-healability and mechanical surface properties by introducing isosorbide oligomer where heterocyclic isosorbide compounds are connected. |
저자 |
김기승1, 김진실1, 문경민1, 홍평화1, 최기원2, 고민재2, 홍성우1
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소속 |
1한국생산기술(연), 2한양대 |
키워드 |
polyurethane; self-healability; isosorbide
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E-Mail |
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