화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 고분자 구조 및 물성
제목 Closed-loop Phase Behavior of Mixtures of Block Copolymers and Homopolymers
초록 The phase diagrams for mixtures consisting of symmetric polystyrene-block-poly (n-pentyl methacrylate) copolymer (PS-PnPMA) and PS (or PnPMA) homopolymers with various molecular weights are presented. The lower disordered-ordered transition (LDOT) and upper ordered-disordered transition (UODT) temperatures of mixtures were determined by polarized optical microscopy, depolarized light scattering and small angle x-ray scattering. The LDOT decreases but UODT increases with increasing amount of PS. Microdomains of the mixtures were examined by transmission electronic microscopy.
저자 김은영1, 김진곤2
소속 1포항공대, 2포항공과대
키워드 closed-loop phase behavior; lower disordered-ordered transition (LDOT); upper ordered-disordered transition (UODT); transition behavior of block copolymer
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