| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 봄 (04/22 ~ 04/23, 대구 EXCO) |
| 권호 |
16권 1호, p.2 |
| 발표분야 |
고분자 |
| 제목 |
Tuned Phase Behavior of polystyrene-block-poly(n-alkyl methacrylate) Copolymers Induced by Random Copolymer for Methacrylate Block |
| 초록 |
The phase behavior of polystyrene-block-poly(n-butyl-ran-n-hexyl) methacrylate (PS-b-Pn(B-r-H)MA) copolymers and polystyrene-block-poly(n-octyl-ran-methyl) methacrylate (PS-b-Pn(O-r-M)MA) copolymers were investigated by using small angle X-ray scattering, birefringence and rheometry. When the total molecular weight and composition of random copolymers were judiciously controlled, the closed-loop consisting of a lower disorder-to-order transition and an upper order-to-disorder transition was observed. The phase behavior by including a random copolymer as one of the blocks was explained by a compressible mean field approach. We found that these block copolymers also exhibited excellent baroplasticity. |
| 저자 |
문홍철1, 한성현1, 조준한2, 김진곤1
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| 소속 |
1포항공과대, 2단국대 |
| 키워드 |
phase behavior; block copolymer; closed-loop
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| E-Mail |
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| 원문파일 |
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