| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
대학원생 구두발표 |
| 제목 |
A versatile linear aliphatic diblock copolyethers platform for selective functionalizations and various nanostructures |
| 초록 |
Well-defined and selectively functionalizable linear aliphatic diblock copolyethers were successfully synthesized without any side reactions from allyl glycidyl ether and ethoxyethyl glycidyl ether by low-temperature anionic ring-opening polymerization with a metal-free catalyst system (which consisted of an alcohol initiator and a phosphazene base promoter) via sequential step feed of the comonomers. Each block of the diblock copolyether selectively underwent deprotection and post chemical functionalizations. Moreover, the diblock copolyethers underwent phase-separation and molecular ordering, and formed various nanostructures, depending on the compositions and selective post chemical modifications. |
| 저자 |
권원상1, 노예철1, Kensuke Kamoshida2, 권경호1, 정윤철1, 김종현1, Hideki Misaka2, 신태주3, 김제한3, 김강우4, 진경식1, 정정운1, 안병철1, 김경태1, 김미희1, 정성민1, 김영용1, 위동우1, 이진석1, 송성진1, 장태현1, 김희수5, Toshifumi Satoh2, Toyoji Kakuchi2, 이문호1
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| 소속 |
1포항공과대, 2Hokkaido Univ., 3가속기 (연), 4가속기(연), 5동국대 |
| 키워드 |
glycidol derivative; phosphazene base catalyst; linear aliphatic diblock copolyethers
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| E-Mail |
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