| 학회 |
한국공업화학회 |
| 학술대회 |
2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터) |
| 권호 |
16권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Deactivation of cobalt supported on pretreated alumina in Fischer-Tropsch synthesis under severe conditions |
| 초록 |
The catalytic deactivation of Co/pretreated-Al2O3 catalysts during Fischer–Tropsch synthesis has been investigated under severe conditions: (1) water added condition in a slurry reactor and (2) high temperature condition in a fixed reactor. The FT catalysts were prepared by using impregnation method with cobalt nitrate precursor on pretreated Al2O3 support (Co/Al, Co/P-Al, Co/Zr-Al, and Co/Zn-Al) .The Co/P-Al catalyst showed relatively low deactivation rate under two severe conditions as compared to the other catalysts. In the water added reactions, it was found that the adsorbed water led to the phase change of alumina surface to boehmite which would enhance oxidizing and restructuring cobalt particles on the support. |
| 저자 |
박선주, 박조용, 우민희, 정규인, 이윤조, 하경수, 전기원
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| 소속 |
한국화학(연) |
| 키워드 |
Fischer–Tropsch synthesis; Co/pretreated-Al2O3; deactivation; boehmite
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| E-Mail |
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