| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.680 |
| 발표분야 |
열역학 |
| 제목 |
Guest-Host Hydrogen Bonding Effect on Thermodynamic stabilities in the binary Clathrate Hydrate with isomeric guest molecules |
| 초록 |
Clathrate hydrates are commonly known for a kind of guest-host compound stabilized by physically stable interaction between guest and host water molecules. A conventional model for predicting hydrate phase equilibrium only concerns physical interactions. However, guest-host interactions need to be more investigated to help understanding their influence on the physicochemical and thermodynamic nature of clathrate hydrate. In the present work, the relation between thermodynamic stability and the guest-host interaction has been studied with isomeric guest molecules, which have similar van der Waals interaction and different probability of hydrogen bond, to investigate the quantitative effect of guest-host hydrogen bond. |
| 저자 |
임동욱1, 박성민1, 노혜윤1, 신규철2, 이 흔1
|
| 소속 |
1KAIST, 2경북대 |
| 키워드 |
clathrate hydrate |
| E-Mail |
|
| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
