화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-에너지저장·변환
제목 Protective layer technology for improving the cycle of Li-S based on high DN salt electrolyte
초록 Uncontrolled growth of insulating lithium sulfide leads to pasivation of sulfur cathodes, which limits high sulfur utilization in lithium-sulfur batteries. Sulfur utilization can be augmented in electrolytes based on solvents with high Gutmann Donor Number; however, violent lithium metal corrosion is a drawback. A salt anion with a high donor number such as bromide or triflate can show better stability with lithium metal and high sulfur utilization. However, instability with lithium metal still remain compared to lithium bis(trifluoromethanesulfonyl)imide. Herein we report that why a salt anion with a high donor number have less stability at lithium anode and combination strategy can solve this problem.
저자 권재형, 김희탁
소속 한국과학기술원
키워드 lithium sulfur; protective layer; high DN anion; additive
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