학회 |
한국화학공학회 |
학술대회 |
2012년 가을 (10/24 ~ 10/26, 부산 BEXCO) |
권호 |
18권 2호, p.2552 |
발표분야 |
촉매 및 반응공학 |
제목 |
Glycerol Steam Reforming over spherical Ni/γ-Al2O3 Catalysts: Effect of Calcination Temperature |
초록 |
Nowadays biodiesel has become one of the more promising carbon neutral biofuels. During the synthesis of biodiesel from biomass such as vegetable oil and palm oil, about 10% of glycerol will be formed as a main by-product. Increasing biomass-derived fuel production has resulted in over-production of glycerol. Therefore there is considerable research interest in converting glycerol to hydrogen or value added chemicals. Steam reforming is one of the common processes to produce synthesis gas or hydrogen from hydrocarbons, alcohols and liquid-phase carbohydrates. However one of the major challenges in nickel steam reforming catalysts is deactivation due to carbon formation. In this work, the effect of calcination temperature on the particle size and carbon formation on spherical γ-Al2O3 supported Ni-based catalysts was investigated in the production of hydrogen by steam reforming of glycerol. |
저자 |
김승훈1, 조수현1, 권송이1, 권태운1, 이승환2, 김방희3, 이관영2, 문동주3
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소속 |
1한국과학기술(연), 2JNK Heaters Co., 3R&D 사업부 |
키워드 |
Glycerol; Steam reforming; Ni-based catalyst; Carbon formation
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E-Mail |
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원문파일 |
초록 보기 |