| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
전기화학 |
| 제목 |
Multi-functional Zwitterionic compounds as additives for electrolyte of lithium secondary battery |
| 초록 |
Zwitterionic compounds containing ester and sulfonyl group have been synthesized and the physical and electrochemical characteristics have been investigated. FT-IR study clearly demonstrates the interaction of Li+ with both of their functional groups. The cell capacity with the addition of either MePyrS or MePipS as an additive dropped , whereas such a sharp decrease of the performance at higher C-rate was not observed when these none-ester-ZWs were replaced by ester-ZWs, implying the positive role of the ester functional group. Most importantly, the pyrrolydinium-based ZWs showed very good cycle perfomance (nealy 90% capacity for 100 cycles). |
| 저자 |
황정민1, 이현주1, 박상준1, 김훈식2, 김홍곤1
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| 소속 |
1한국과학기술(연), 2경희대 |
| 키워드 |
zwitterion; electrolyte additive; ionic liquids; lithium secondary battery
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| E-Mail |
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