| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
| 권호 |
14권 2호, p.3464 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Positive effect of phosphorus modification on the cobalt-based Fischer-Tropsch catalysts |
| 초록 |
The effect of phosphorus modification on the cobalt-based Fischer-Tropsch (F-T) catalysts such as Co/P-Al2O3, Co/ZrP/SiO2 and Co/AlPO4 was investigated. The activities of the catalysts were compared with the unmodified Co/Al2O3 and Co/Zr/SiO2 catalysts. Positive effects with respect to CO conversion and C5+ selectivity are observed in all F-T catalysts with a moderate amount of phosphorus addition on Al2O3 and SiO2 support. The catalysts have been characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), temperature programmed reduction (TPR), hydrogen chemisorption, surface area measurement and pore size distribution. The enhanced catalytic performances during F-T synthesis are related to the cobalt cluster size and its reducibility on the phosphorus modified Al2O3 and SiO2 support. |
| 저자 |
배종욱, 김승문, 오종혁, 박선주, 이윤조, 전기원
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| 소속 |
한국화학(연) |
| 키워드 |
Fischer-Tropsch Synthesis; phosphorus modification; cobalt-based catalyst
|
| E-Mail |
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| 원문파일 |
초록 보기 |
