화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 고분자구조 및 물성
제목 Study of Electrical Memory Characteristics of an Oxadiazole-based Brush Polymer in Nanoscale Thin Films
초록 The self-assembly characteristics in nanoscale thin films and electrical memory behaviors of PPOXBPA, a well-defined brush polymer based oxadiazole moieties were investigated. The synchrotron grazing incidence X-ray scattering analysis found that the brush polymer molecules in thin films formed a multibilayer structure based on a fully extended backbone and bristle conformation. The as-cast films had a relatively low crystallinity and formed a vertical multibilayer structure with a broad orientational distribution, whereas the thermal-annealed films had a high crystallinity and formed an almost perfectly horizontal-oriented multibilayer structure. These different morphologies led different electrical memory modes in devices; the as-cast films revealed volatile memory behavior, whereas the thermal-annealed films showed permanent memory characteristics. This brush polymer is programmable volatile and nonvolatile memory devices via control of the morphological structure.
저자 이진석, 권원상, 안병철, 김용진, 김영용, 고용기, 정성민, 권경호, 김종현, 위동우, 송성진, 김창섭, 이종찬, 이호열, Brian J. Ree, 윤현경, 이문호
소속 포항공과대
키워드 oxadiazole-containing brush polymer; self-assembly; multibilayer structure; grazing incidence X-ray scattering; digital memory behaviors
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