| 학회 |
한국공업화학회 |
| 학술대회 |
2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center)) |
| 권호 |
24권 1호 |
| 발표분야 |
포스터-촉매 |
| 제목 |
Radicals Anchored on Transition Metal Oxides for the Elimination of Aqueous Pollutants |
| 초록 |
SO4•- is deemed as an oxidant complementary to •OH in degrading recalcitrant contaminants because SO4•- provides a longer lifespan compared to •OH, albeit possessing such oxidizing ability comparable each other. We previously envisioned an interesting radicalization pathway, in which SO42- species are anchored on metal oxide surface and are transformed into SO4•- analogues via •OH ↔ SO4•- inter-conversion. SO4•- species are then utilized to decompose aqueous pollutants. This presentation showcases our mechanistic study on the novel radicalization pathway, where SO42--functionalized metal oxide surface is initially computed for the observation of energetics altered. Reaction runs under fine-tuned environments served to identify the rate-determining step to dominate the overall radicalization pathway and to corroborate that •OH ↔ SO4•- is of high plausibility. |
| 저자 |
최윤정, 김상훈, 김종식
|
| 소속 |
한국과학기술(연) |
| 키워드 |
radical transfer; SO4•-; •OH
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| E-Mail |
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