| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Characterization of Digital Memory Behaviors of Donor-Acceptor Type π-Conjugated Polymer Systems |
| 초록 |
The π-conjugated donor-acceptor type polymers Fl-TPA, Fl-TPA-TCNE and Fl-TPA-TCNQ, which are composed of fluorine (Fl), triphenylamine (TPA), dimethylphenylamine, alkyne, alkyne-tetracyanoethylene (TCNE) and alkyne-7,7,8,8-tetracyanoquinodimethane (TCNQ) adduct, were synthesized. These polymers thermally stable up to 291~409 oC. Molecular orbital levels and band gaps are depending on donor-acceptor composition in the π-conjugated polymer. Interestingly, TCNE and TCNQ units were found to diversify the digital memory modes and to widen the active polymer layer thickness window. Fl-TPA polymer exhibits stable unipolar permanent memory behavior with high reliability. F1-TPA-TCNE and Fl-TPA-TCNQ devices exhibit exhibits stable unipolar permanent memory behavior as well as dynamic random access memory (DRAM) behavior. This study has demonstrated that π-conjugated cyano moieties is approach for the design and synthesis of high-performance digital memory polymers. |
| 저자 |
송성진1, 고용기1, 김동민1, 김경태1, 정성민1, 위동우1, 김영용1, 권경호1, 이진석1, 김종현1, 이종찬1, 김창섭1, 김용진1, 이호열1, 윤현경1, Brian Jiwon Ree1, Tsuyoshi Michinobu2, 이문호1
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| 소속 |
1포항공과대, 2Tokyo Institute of Technology |
| 키워드 |
Conjuageted polymer; memory device; Donor-acceptor
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| E-Mail |
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