화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 분자전자 부문위원회 II
제목 Facile Solution Shearing Process for Tuning Crystallinity and Alignment of Organic Semiconductor
초록 In this study, we introduce an evaporative assembly method to control the growth of the crystalline organic material for high-quality organic semiconductor patterns. We used flow coating method, which utilizes the phenomenon of the “coffee ring effect” coupled with a convective flow and a controlled stick-slip motion. The crystallinity and alignment of materials impacts on properties of organic field-effect transistors (OFETs). Therefore, to uniform alignment of 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS-PEN) crystal and its size, flow coating was used with different shear stress. The property of crystal were determined with p-OM, pUV, GIWAX, and NEXAFS. Furthermore, through anisotropic p-UV absorption spectrums, one-directional solution shearing causing a crystal aligned morphology was explained. The intensity of crystal was verified its tendency through X-ray diffraction.
저자 남기범1, xinlin Li2, 김경훈3, 이재빈1, 김언지1, 김세현4, 이동윤1
소속 1경북대, 2Qingdao Univ., 3포항공과대, 4영남대
키워드 flow coating; evaporative self assembly; TIPS-pentacene
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