화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 고분자합성
제목 A New Poly(aryleneethynylene)s from the Cross-Coupling Condensation of 1,6-heptadiynes and p-diiodobenzene
초록 Poly(fluorenyleneethynylene)s had been prepared by alkyne metathesis of (9,9-dialkyl)fluoren-2,7-yleneethynylenes. Poly(arylene-ethynylene)s with ferrocene unit were also synthesized by the reaction of 1,1’-bis(ethynyldimethylsilyl)ferrocene and aromatic dihalides. Here, we report the synthesis of a new poly(aryleneethynylene)s from the cross-coupling condensation of 4-[(tert-butyldimethylsiloxy)methyl]-1,6-heptadiyne and p-diiodobenzene. And its electro-optical and electrochemical properties were measured and discussed.
저자 제갈영순1, 박종욱2, 진성호3
소속 1경일대, 2가톨릭대, 3부산대
키워드 Conjugated polymer; 1; 6-heptadiyne; poly(aryleneethynylene); photoluminescence; cyclic voltammogram
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