화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 고분자_포스터
제목 Process design for lithium recovery using bipolar membrane electrodialysis system
초록 This study object to evaluate the effect of LMO (lithium manganese oxide) and enhanced BEDI (bipolar membrane electro-dialysis deionization) on the lithium ion desorption process for the recovery of lithium ions. The factors for lithium ion recovery are evaluated in reference to the pH, voltage, flow rates, and number of bipolar membrane sheets to present the optimal conditions. The research findings show that in desorption of LMO lithium ions, the lower the pH, the higher the desorption rates. When the voltage was 6.5 V per sheet, desorption rates were approximately 70%, and when flow rates were 0.44 mL/cm2·min, desorption was approximately 30 minutes faster than that at other flow rates. When the number of bipolar membrane sheets was 4, it was possible to control 4 the pH to under 4, a level at which lithium ions adsorbed onto LMO might affect the desorption phenomenon. For a combination of the conditions above, the desorption efficiency of lithium ions was approximately 70%, and the recovery time was reduced by approximately 180 minutes compared to when a chemical process was used for lithium ion desorption.
저자 황택성1, 손원근2, 현승미1, 김인식1
소속 1충남대, 2시온텍
키워드 Electrodialysis; Bipolar membrane; Lithium manganese oxide; Electrical desorption proces
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