화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX)
권호 15권 2호, p.1512
발표분야 분리기술
제목 Reactive extraction of succinic acid using a hollow fiber membrane contactor with TOA/1-octanol solution
초록 Succinic acid, a four carbon dicarboxylic acid, has attracted a great deal of attention for many years because it can be used as a raw material for biodegradable polymer. As an alternative to the petrochemical-based process, the intensive study on organic acid production through the fermentation process is currently proceeding. In this study, we investigated reactive extraction of succinic acid from aqueous solution with tri-n-octylamine(TOA) in 1-octanol. We verified the effect of flow rate, concentration of TOA, initial concentration of succinic acid and pH of aqueous solution on forward extraction and also effect of flow rate and concentration of stripping solution on backward extraction. The effect of TOA concentration on forward extraction was dominant among the various operating variables considered. At the pH above the pKa1 value, extraction performance was significantly reduced and even more above pKa2 approaching zero in extraction performance.
저자 김동현, 전영시, 이은주, 홍원희
소속 한국과학기술원
키워드 reactive extraction; succinic acid; hollow fiber membrane
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