학회 |
한국고분자학회 |
학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
권호 |
43권 2호 |
발표분야 |
대학원생 구두발표(발표15분) |
제목 |
Solution-precessable, thin and high-dielectric polyurea gate insulator with strong hydrogen bonding for low-voltage organic thin-film transistors |
초록 |
We report on the fabrication of polyurea (PU) gate insulator capable of solution process for low-voltage operation and high performance organic thin-film transistors (TFTs). We synthesized solution-processable polyurea by precisely controlling hydrogen bonding through molecular design and molecular weight. A 60 nm-thick PU thin film exhibited high dielectric constant of 5.82 and excellent electrical insulating properties. To investigate the potential of the PU thin film as a gate insulator, we fabricated flexible dinaphtho[2,3-b:20,30-f]thieno[3,2-b]thiophene (DNTT) organic thin-film transistors (OTFTs). The DNTT TFTs with the 60 nm-thick PU gate insulator showed excellent TFT performance with a field-effect mobility at a low operation voltage below 3V. In addition, the mobility of DNTT TFTs significantly improved with simple metal-oxide assisted surface treatment on PU gate insulator. These flexible TFT devices were successfully operated after 1000-times bending test. |
저자 |
유성미1, 김동균1, 하태욱1, 원종찬1, 장광석2, 김윤호1
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소속 |
1한국화학(연), 2한양대 |
키워드 |
Gate insulators; Polyurea; Organic thin-film transistors;
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E-Mail |
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