화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 대학원생 구두발표(발표15분)
제목 Solution-precessable, thin and high-dielectric polyurea gate insulator with strong hydrogen bonding for low-voltage organic thin-film transistors
초록 We report on the fabrication of polyurea (PU) gate insulator capable of solution process for low-voltage operation and high performance organic thin-film transistors (TFTs). We synthesized solution-processable polyurea by precisely controlling hydrogen bonding through molecular design and molecular weight. A 60 nm-thick PU thin film exhibited high dielectric constant of 5.82 and excellent electrical insulating properties. To investigate the potential of the PU thin film as a gate insulator, we fabricated flexible dinaphtho[2,3-b:20,30-f]thieno[3,2-b]thiophene (DNTT) organic thin-film transistors (OTFTs). The DNTT TFTs with the 60 nm-thick PU gate insulator showed excellent TFT performance with a field-effect mobility at a low operation voltage below 3V. In addition, the mobility of DNTT TFTs significantly improved with simple metal-oxide assisted surface treatment on PU gate insulator. These flexible TFT devices were successfully operated after 1000-times bending test.
저자 유성미1, 김동균1, 하태욱1, 원종찬1, 장광석2, 김윤호1
소속 1한국화학(연), 2한양대
키워드 Gate insulators; Polyurea; Organic thin-film transistors;
E-Mail