| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO)) |
| 권호 |
25권 1호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Cross-linked Sulfonated Poly(arylene ether sulfone) containing Bishydroxy Perfluoropolyether Cross-linker for Polymer Electrolyte Membrane Water Electrolysis Applications. |
| 초록 |
The cross-linked sulfonated poly(arylene ether sulfone) (C-SPAES) membrane is fabricated by effective cross-linking method using bishydroxy perfluoropolyether (PFPE) as a cross-linker for polymer electrolyte membrane water electrolysis applications. The C-SPAES membrane shows reasonably high proton conductivity compared to linear SPAES membrane. In addition, the cross-linked structure using PFPE improves physicochemical stability of SPAES. Under, 90 oC and 50 % RH conditions, membrane electrode assembly (MEA) employing the C-SPAES membrane shows an outstanding cell performance (1.17 W cm-2 at 0.65 V) due to the interfacial compatibility between the electrode containing perfluoro polymer as a binder and C-SPAES membrane containing the perfluorinated moieties. Furthermore, in the wet/dry cycling test at 90 oC, the MEA employing the C-SPAES membrane reveals notable durability. |
| 저자 |
고한솔1, 김미정1, 황선수1, 정유경1, 이종찬2, 김기현1
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| 소속 |
1경상국립대, 2서울대 |
| 키워드 |
cross-linking; perfluoropolyether; polymer electrolyte membrane; water electrolysis
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| E-Mail |
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