학회 | 한국공업화학회 |
학술대회 | 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
권호 | 23권 2호 |
발표분야 | 포스터_환경·에너지 |
제목 | Investigation of the coalescence phase between mesophase spheres during mesophase formation |
초록 | The molecular weight of the pitch increases with the synthesis conditions (temperature, time, pressure). Between the components having a molecular weight more than 2,500 amu laminated by Van der Waals force, this region is called mesophase. In general, mesophase forms a bulk mesophase through the formation and growth of mesogen and coalescence between mesophase spheres. Therefore, sufficient reaction conditions for mesogen formation and proper viscosity for coalescence between mesophase spheres are important factors for forming bulk mesophase. In this paper, the mechanism of coalescence between mesophase spheres during the bulk mesophase formation is discussed. The following two mechanisms were proposed as the coalescing mechanism of mesophase spheres. 1) Polymerization of low boiling point components in pitch, 2) Reduction of isotropic area by volatilization. To visually confirm this process, mesophase pitch and isotropic pitch were mixed at a mass ratio of 8:2, 6:4, 4:6, and 2:8. |
저자 | 최윤정1, 김지홍1, 이승은1, 이영석2, 임지선1 |
소속 | 1한국화학(연), 2충남대 |
키워드 | mesophase pitch; spherical graphite; polarizing microscope |