학회 |
한국고분자학회 |
학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
권호 |
38권 1호 |
발표분야 |
고분자합성 |
제목 |
Synthesis of chemically and thermally advanced nonvolatile polyimide memorys |
초록 |
A new diamine monomer having carbazole group (HAB-CBZ) was prepared from 3,3′-dihydroxy-4,4′-diaminobiphenyl via consecutive reaction – phthalic imidization, Mitsumobu reaction and reduction, 3,30-bis[9-carbazole(ethyloxy)biphenyl]-4,40-diamine (HAB-CBZ) by polycondensation with four different aromatic dianhydrides: pyromellitic dianhydride (PMDA), 3,30,4,40-biphenyltetracarboxylic dianhydride (BPDA), 3,30,4,40-diphenylethertetracarboxylic dianhydride (ODPA), and 3,30,4,40-diphenylsulfonyltetracarboxylic dianhydride (DSDA). From the precursors, nanoscale thin films of polyimides (PIs) were prepared by spin-coating and subsequent thermal imidization. All the PIs exhibited excellent thermal and dimensional stability. In particular, the PIs based on the PMDA and BPDA units revealed excellent chemical resistance to organic solvents, in addition to the high thermal and dimensional stability. |
저자 |
권경호1, 박삼대1, 김진철1, 정정운1, 노예철1, 권원상1, 안병철1, 김경태1, 김미희1, 고용기1, 정성민1, 김영용1, 위동우1, 김종현1, 송성진1, 김창섭1, 이종찬1, Nguyen Thi Phuong Thu1, 이윤철1, 김용진1, 손보경1, Graniel Harne A.Abrenica1, 김희수2, 이문호1
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소속 |
1포항공과대, 2동국대 |
키워드 |
insoluble polyimide; nanoscale thin film; electrically nonvolatile memory
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E-Mail |
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