| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Supramolecular polymer electrolyte with fast molecular shuttles for solid-state lithium batteries |
| 초록 |
The fast molecular shuttle inside a supramolecular polymer can enhance the ionic conductivity and charge transport capability of the solid polymer electrolyte and maintain mechanically tough properties. The supramolecular polymer electrolyte with fast molecular shuttles exhibits high ionic conductivity (σ＞1 mS cm−1), Li+-ion transference number (t+=0.71), and electrochemical oxidation stability (≈4.7 V versus Li+/Li) at room temperature. Applications of the polymer electrolyte in LiFePO4-Li, LiNi0.8Mn0.1Co0.1O2-Li, and LiNi0.8Mn0.1Co0.1O2-graphite batteries further demonstrate that high Coulombic efficiency (≥98.5%) with excellent rate-capability and quick charge performance (≥2C) can be achieved with a fast molecular shuttle design. |
| 저자 |
서지애, 이광희, 허준, 성명창, 서지훈, 김동완
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| 소속 |
고려대 |
| 키워드 |
Supramolecular polymer; electrolyte; molecular shuttle; Li-ion battery
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| E-Mail |
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