화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2005년 가을 (10/28 ~ 10/29, 건국대학교)
권호 9권 2호
발표분야 정밀화학
제목 Surface properties of fluorinated latex films
초록 The surface properties of copolymer latex films prepared by batch-type emulsion polymerization of perfluoroalkyl acrylate and hydrocarbon-based alkyl methacrylate were investigated by means of contact angle and sliding angle measurements. The hydrophobicity of the latex films was estimated from contact angles of water and was proportional to the fluorine content at the surface measured by X-ray photoelectron spectroscopy. The roughness and chemical composition of latex film surfaces were considered in order to explain sliding behavior of water droplet on the latex films. It was concluded that the chemical heterogeneity resulted from chain architecture was mainly responsible for the experimental observations by governing effective segregation of perfluoroalkyl groups at the surface. On the other hand, the effect of small surface roughness was negligible for the sliding angle of water droplet in the present study.
저자 하종욱, 박인준, 이수복
소속 한국화학(연)
키워드 latex film; perfluoroalkyl; surface properties
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