화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.2146
발표분야 열역학
제목 Phase behaviour of the ternary mixture system of Stereocomplex, dichloromethane and carbon dioxide
초록 Phase behavior data are presented for Stereocomplex (PLLA 50% / PDLA 50%)  in supercritical mixtures of dichloromethane and carbon dioxide. Cloud point pressures were measured using a variable-volume view cell apparatus as functions of temperature, dichloromethane composition in a mixed solvent, molecular weight of PLLA at the polymer concentration of 0.01, 0.02 mass fraction in solution, and for temperatures up to about 363.15K. This system exhibited the characteristics of lower critical solution temperature phase behavior.
저자 권정민1, 김학민1, 김수현2, 김화용1
소속 1서울대, 2한국과학기술(연)
키워드 Supercritical carbon dioxide; Polymer–solvent–gas ternary systems; Variable volume view cell; Biodegradable polymer; Stereocomplex
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